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There are 15 nine-letter words containing 2A, P, T and V

CAPTIVATEcaptivate v. To attract and hold (someone’s) interest and attention; to charm.
captivate v. (Obsolete) To take prisoner; to capture; to subdue.
CAPTIVATE v. to charm, fascinate.
EVAPORATEevaporate v. (Transitive, intransitive) to transition from a liquid state into a gaseous state.
evaporate v. (Transitive) to expel moisture from (usually by means of artificial heat), leaving the solid portion.
evaporate v. (Transitive, figuratively) to give vent to; to dissipate.
PALSTAVESpalstaves n. Plural of palstave.
PALSTAVE n. (Dutch) a peculiar bronze adz, used in prehistoric Europe about the middle of the Bronze Age, also PALSTAFF.
PARAVANTSPARAVANT n. a preeminent person or thing.
PARAVAUNTparavaunt adv. (Obsolete) perhaps; peradventure.
PARAVAUNT adv. (Spenser) before, in front, also PARAVANT.
PASSIVATEpassivate v. (Chemistry) to reduce the chemical reactivity of a surface by applying a coating.
PASSIVATE v. to coat metal with oxides to protect from corrosion.
PLACATIVEplacative adj. (Chiefly US) That placates; pacifying.
PLACATIVE adj. tending to placate, also PLACATORY.
POSTCAVAEpostcavae n. Plural of postcava.
POSTCAVA n. (Latin) a vein in higher vertebrates.
POSTCAVALpostcaval adj. (Anatomy) Posterior to the vena cava.
postcaval n. (Anatomy) A postcaval vein.
POSTCAVAL adj. relating to the postcava, the inferior vena cava.
POSTCAVASPOSTCAVA n. (Latin) a vein in higher vertebrates.
VALPROATEvalproate n. (Chemistry, pharmacology) Any salt or ester of valproic acid.
VALPROATE n. a salt of valproic acid.
VAMPLATESvamplates n. Plural of vamplate.
VAMPLATE n. a hand guard.
VANASPATIvanaspati n. (Botany) Any plant that bears fruits but no evident flowers.
Vanaspati prop.n. (Music) Name of a rāgam in Carnatic music. It is the fourth melakarta rāgam of the 72 melakarta rāgams…
VANASPATI n. (Sanskrit) a hydrogenated vegetable fat used as a butter substitute.
VAPULATEDvapulated v. Simple past tense and past participle of vapulate.
VAPULATE v. to flog; to be flogged.
VAPULATESvapulates v. Third-person singular simple present indicative form of vapulate.
VAPULATE v. to flog; to be flogged.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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