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There are 19 twelve-letter words containing 4A, I and N

ADAPTATIONALadaptational adj. Relating or pertaining to adaptation, or the adjustment of one thing to another; adaptive.
adaptational adj. (Biology) Applied to physiological or functional modifications of parts or organs, as distinguished…
ADAPTATIONAL adj. relating to adaptation.
AMALGAMATINGamalgamating v. Present participle of amalgamate.
AMALGAMATE v. to unite in or as if in an amalgam; esp. to merge into a single body.
AMALGAMATIONamalgamation n. The process of amalgamating; a mixture, merger or consolidation.
amalgamation n. The result of amalgamating; a mixture or alloy.
amalgamation n. (Obsolete) The intermarriage and interbreeding of different ethnicities or races.
ANACATHARSISanacatharsis n. (Medicine) vomiting or expectoration.
ANACATHARSIS n. vomiting.
ANACATHARTICanacathartic n. An expectorant or emetic medicine.
ANACATHARTIC n. a drug causing vomiting or expectoration.
ANAGRAMMATICanagrammatic adj. Being or relating to an anagram.
ANAGRAMMATIC adj. like an anagram, also ANAGRAMMATICAL.
ANAPAESTICALanapaestical adj. Anapestic.
ANAPAESTICAL adj. in the form of an anapaest, two short metrical syllables followed by one long one.
ANTIMACASSARantimacassar n. A cover for the back or arms of a chair or sofa, originally to prevent them from being soiled by macassar oil.
ANTIMACASSAR n. a cover to protect the back or arms of furniture.
ANTIMALARIALantimalarial n. An agent that prevents or counteracts malaria.
antimalarial adj. Preventing or counteracting malaria.
ANTIMALARIAL adj. effective against malaria, also ANTIMALARIA.
ARMAMENTARIAarmamentaria n. Plural of armamentarium.
ARMAMENTARIUM n. the collection of equipment and techniques available to one in a particular field, esp. in medicine.
ASPARAGINASEasparaginase n. (Biochemistry) An enzyme that catalyzes the hydrolysis of asparagine to aspartic acid, used in chemotherapy.
ASPARAGINASE n. an enzyme that causes asparagine to hydrolyse to aspartic acid and ammonia.
BACCHANALIANbacchanalian adj. Alternative letter-case form of Bacchanalian.
bacchanalian n. Alternative letter-case form of Bacchanalian.
Bacchanalian adj. Of or pertaining to the festival of Bacchus; relating to or given to reveling and drunkenness.
BACCHANALIASbacchanalias n. Plural of bacchanalia.
CARAVANSARAIcaravansarai n. Alternative spelling of caravanserai.
CARAVANSARAI n. a kind of unfurnished inn or extensive enclosed courtyard where caravans stop, also CARAVANSARY, CARAVANSERAI.
CARAVANSERAIcaravanserai n. A roadside inn having a central courtyard where caravans can rest.
caravanserai n. (Humorous) An upscale hotel.
caravanserai n. A home or shelter for caravans.
PARATANIWHASPARATANIWHA n. (Maori) a New Zealand plant with pink and red serrated leaves.
RASTAFARIANSRastafarians n. Plural of Rastafarian.
RASTAFARIAN n. a member of rastafari, a West Indian cult which rejects western ideas and regards the Emperor Haile Selassie as divine.
SALAMANDRIANsalamandrian adj. Of, relating to, or resembling a salamander, the genus Salamandra, or the family Salamandridae.
SALAMANDRIAN n. a salamander of the order Batrachia.
TARANTARAINGTARANTARA v. to make the sound of a trumpet or horn.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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