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There are 12 fourteen-letter words containing M, P, R, S and X

APPROXIMATIONSapproximations n. Plural of approximation.
APPROXIMATION n. the act of drawing together.
DEMULTIPLEXERSdemultiplexers n. Plural of demultiplexer.
DEMULTIPLEXER n. an electronic device that separates a multiplex signal into its component parts.
EXPERIMENTISTSexperimentists n. Plural of experimentist.
EXPERIMENTIST n. a person who carries out experiments.
EXPRESSIONISMSexpressionisms n. Plural of expressionism.
EXPRESSIONISM n. a theory or practice in art of seeking to depict the subjective emotions and responses that objects and events arouse in the artist.
EXTEMPORANEOUSextemporaneous adj. With inadequate preparation or without advance thought; offhand.
EXTEMPORANEOUS adj. unpremeditated; esp. of prayer, discourse, composition, etc., also EXTEMPORARY, EXTEMPORE.
MORPHOSYNTAXESmorphosyntaxes n. Plural of morphosyntax.
MORPHOSYNTAX n. the study of the interaction of morphology and syntax.
PNEUMOTHORAXESpneumothoraxes n. Plural of pneumothorax.
PNEUMOTHORAX n. accumulation of air or gas in the pleural cavity.
PREEXPERIMENTSpreexperiments n. Plural of preexperiment.
PREMAXILLARIESpremaxillaries n. Plural of premaxillary.
PREMAXILLARY n. the premaxilla, a bone in front of the maxilla, also PREMAXILLA.
SUPRAMAXILLARYsupramaxillary adj. (Anatomy) Situated over the lower jaw.
supramaxillary adj. (Anatomy) Of or pertaining to the upper jaw.
supramaxillary n. (Anatomy) The superior maxillary, or upper jawbone.
XEROPHTHALMIASxerophthalmias n. Plural of xerophthalmia.
XEROPHTHALMIA n. extreme dryness of the conjunctive, thought to stem from a vitamin A deficiency, also XEROMA.
XIPHIHUMERALISxiphihumeralis n. A long, flat strip of pectoral muscle comprising a band of parallel fibres, found in felines.
XIPHIHUMERALIS n. in vertebrates, a muscle leading from the xiphoid cartilage to the humerus.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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