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There are 7 nine-letter words beginning with BIV

BIVALENCEbivalence n. The state or quality of being bivalent (in any sense).
BIVALENCE n. the state of being bivalent, having a valency of two, also BIVALENCY.
BIVALENCYbivalency n. The quality of being bivalent.
BIVALENCY n. the state of being bivalent, having a valency of two, also BIVALENCE.
BIVALENTSbivalents n. Plural of bivalent.
BIVALENT n. a pair of chromosomes, also DIVALENT.
BIVALVATEbivalvate adj. Having the form of a bivalve: consisting of or incorporating two matching hinged or folding parts.
BIVALVATE adj. of molluscs, having two valves.
BIVARIANTbivariant adj. (Mathematics) Having two independent variables.
bivariant adj. (Programming) Both covariant and contravariant.
BIVARIANT adj. involving two variables.
BIVARIATEbivariate adj. (Mathematics) Having or involving exactly two variables.
bivariate n. (Mathematics) A polynomial or function with exactly two variables.
BIVARIATE adj. involving or depending on two variables.
BIVOUACKSbivouacks n. Plural of bivouack.
bivouacks v. Third-person singular simple present indicative form of bivouack.
BIVOUAC v. (French) to spend the night in a makeshift camp without tents etc.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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