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There are 2 six-letter words beginning with CAPT

CAPTAN• captan n. A particular phthalimide fungicide.
• captan n. (Chemistry) Ethyl mercaptan.
• CAPTAN n. a type of agricultural fungicide produced from mercaptan.
CAPTOR• captor n. One who is holding a captive or captives.
• captor n. One who catches or has caught or captured something or someone.
• CAPTOR n. one who takes or holds a captive.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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