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There are 3 five-letter words beginning with DIO

DIODEdiode n. (Electronics) An electronic device that allows current to flow in one direction only; used chiefly as a rectifier.
DIODE n. a type of electron tube.
DIOLSdiols n. Plural of diol.
DIOL n. an alcohol with two hydroxyl groups in the molecule.
DIOTAdiota n. (Historical, Roman antiquity) A vase or drinking cup with two handles.
Diota prop.n. A taxonomic genus within the family Erebidae – certain tiger moths.
DIOTA n. (Greek) an ancient two-handled vase.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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