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There are 6 words beginning with ORPI

ORPIMENT	• orpiment n. Arsenic trisulphide, occurring naturally in crystals or massive deposits, formerly used as a dye or pigment. • ORPIMENT n. a yellow arsenic compound used as a pigment.
ORPIMENTS	• orpiments n. Plural of orpiment. • ORPIMENT n. a yellow arsenic compound used as a pigment.
ORPIN	• orpin n. Alternative form of orpine (“the plant or the pigment”). • ORPIN n. a yellow pigment of various degrees of intensity, approaching also to red.
ORPINE	• orpine n. Any of several temperate succulent plants of the family Crassulaceae, that have clusters of purple flowers… • orpine n. A yellow pigment of various degrees of intensity, sometimes approaching red. • ORPINE n. a kind of stonecrop, aka livelong.
ORPINES	• orpines n. Plural of orpine. • ORPINE n. a kind of stonecrop, aka livelong.
ORPINS	• ORPIN n. a yellow pigment of various degrees of intensity, approaching also to red.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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English Wiktionary: 8 words
Scrabble in French: 4 words
Scrabble in Spanish: no word
Scrabble in Italian: 2 words
Scrabble in German: no word
Scrabble in Romanian: 12 words

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