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There is only one ten-letter word beginning with PIO

PIONEERINGpioneering v. Present participle of pioneer.
pioneering adj. Involving accomplishments or activities that have not been done before, or developing or using new methods…
pioneering n. The activity of the verb pioneer.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org.

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