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There are 4 ten-letter words beginning with RAF

RAFFINATESraffinates n. Plural of raffinate.
RAFFINATE n. the refined fraction which results after removal of impurities by solvent extraction, specifically in oil refining.
RAFFINOSESraffinoses n. Plural of raffinose.
RAFFINOSE n. a colorless crystalline slightly sweet substance obtained from the molasses of the sugar beet.
RAFFLESIASrafflesias n. Plural of rafflesia.
RAFFLESIA n. any of various stemless leafless parasitic plants, native to Java and Sumatra.
RAFTERINGSrafterings n. Plural of raftering.
RAFTERING n. rafters collectively.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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