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There are 4 twelve-letter words beginning with SUBSTI

SUBSTITUENTS	• substituents n. Plural of substituent. • SUBSTITUENT n. a thing, esp. an atom, substituted for another.
SUBSTITUTING	• substituting v. Present participle of substitute. • SUBSTITUTE v. to put or use in the place of another.
SUBSTITUTION	• substitution n. The act of substituting or the state of being substituted. • substitution n. A substitute or replacement. • substitution n. (Chemistry, especially organic chemistry) The replacement of an atom, or group of atoms, in a compound, with another.
SUBSTITUTIVE	• substitutive adj. Characteristic of, or serving as a substitute. • SUBSTITUTIVE adj. serving or suitable as a substitute.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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See this list for:

English Wiktionary: 11 words
Scrabble in French: 12 words
Scrabble in Spanish: 17 words
Scrabble in Italian: no word
Scrabble in German: no word
Scrabble in Romanian: 20 words

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