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There are 8 thirteen-letter words beginning with SUBSTANT

SUBSTANTIALLY	• substantially adv. In a strong substantial manner; considerably. • substantially adv. To a great extent; in essence; essentially. • substantially adv. Without material qualifications.
SUBSTANTIATED	• substantiated v. Simple past tense and past participle of substantiate. • SUBSTANTIATE v. to give substance or form to.
SUBSTANTIATES	• substantiates v. Third-person singular simple present indicative form of substantiate. • SUBSTANTIATE v. to give substance or form to.
SUBSTANTIATOR	• substantiator n. One who or that which substantiates. • SUBSTANTIATOR n. one who substantiator.
SUBSTANTIVELY	• substantively adv. In a substantive manner, or to a substantive extent. • substantively adv. (Grammar, of a word) Employed as a noun. • SUBSTANTIVE adv. relating to substance.
SUBSTANTIVISE	• substantivise v. (Grammar) To use as or convert into a substantive (noun). • SUBSTANTIVISE v. to make substantive, also SUBSTANTIVIZE.
SUBSTANTIVITY	• substantivity n. The state of being substantive. • substantivity n. The ability of a chemical or dye to stick to a target. • SUBSTANTIVITY n. the state of being substantive.
SUBSTANTIVIZE	• substantivize v. American spelling and Oxford British spelling standard spelling of substantivise. • SUBSTANTIVIZE v. to make substantive, also SUBSTANTIVISE.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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See this list for:

English Wiktionary: 13 words
Scrabble in French: 9 words
Scrabble in Spanish: 8 words
Scrabble in Italian: no word
Scrabble in German: no word
Scrabble in Romanian: 19 words

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