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There are 5 eight-letter words beginning with VALE

VALENCES• valences n. Plural of valence.
• VALENCE n. a chemical bond, also VALENCY.
VALENCIA• valencia n. A kind of woven fabric for waistcoats, having the weft of wool and the warp of silk or cotton.
• Valencia prop.n. The capital city of the autonomous community of Valencia, Spain.
• Valencia prop.n. An autonomous community of Spain, the Valencian Community.
VALERATE• valerate n. (Chemistry) any salt or ester of valeric acid.
• VALERATE n. a salt of valeric acid.
VALERIAN• valerian n. A hardy perennial flowering plant, Valeriana officinalis, with heads of sweetly scented pink or white flowers.
• valerian n. More generally, any plant of the genus Valeriana.
• valerian n. (Uncountable) The root of Valeriana officinalis, used in herbal medicine.
VALETING• valeting v. Present participle of valet.
• VALETING n. the act of being a valet.

Scrabble words — in black are valid world wide — in RED are not valid in North America — in GREEN are valid only in North America.
Definitions are short excerpt from the WikWik.org and 1Word.ws.

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